Osmotic Pressure and Electrochemical Potential

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Brownian motion, hydrodynamics, and the osmotic pressure

It is shown that the osmotic pressure of a colloidal dispersion can be interpreted as the isotropic part of the macroscopic particle stress in the suspension. The particle stress is in turn expressible in terms of hydrodynamic interactions among the suspended particles. Thus, there is a completely mechanical definition of the osmotic pressure, just as there is for the pressure in a molecular fl...

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5 Weissmann, C., P. Borst, R. H. Burdon, M. A. Billeter, and S. Ochoa, these PROCEEDINGS, 51, 682 (1964). 6Ibid., 890 (1964). 7Burdon, R. H., P. Borst, and C. Weissmann, Federation Proc., 23, 319 (1964). 8 Ochoa, S., C. Weissmann, P. Borst, R. H. Burdon, and M. A. Billeter, Federation Proc., in press. 9 Fenwick, M. L., R. L. Erikson, and R. M. Franklin, Federation Proc., 23, 319 (1964). '0Kaern...

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ژورنال

عنوان ژورنال: Journal of Chemical Education

سال: 1996

ISSN: 0021-9584,1938-1328

DOI: 10.1021/ed073pa294.2